Agricola, Georgius, De re metallica, 1912/1950

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1good, for the cupels made from them, since they are not sufficiently dry,
frequently
crack and break in the fire and absorb the metals.
If ashes of
beech
or similar wood are not to be had, the assayer makes little balls of such
ashes
as he can get, after they have been cleared of impurities in the manner
before
described, and puts them in a baker's or potter's oven to burn, and from
these
the cupels are made, because the fire consumes whatever fat or damp
there
may be.
As to all kinds of ashes, the older they are the better, for it is
necessary
that they should have the greatest possible dryness.
For this
reason
ashes obtained from burned bones, especially from the bones of the
heads
of animals, are the most suitable for cupels, as are also those ashes
obtained
from the horns of deer and the spines of fishes.
Lastly, some take the
ashes
which are obtained from burnt scrapings of leather, when the tanners
scrape
the hides to clear them from hair.
Some prefer to use compounds,
that
one being recommended which has one and a half parts of ashes from the
bones
of animals or the spines of fishes, and one part of beech ashes, and half a
part
of ashes of burnt hide scrapings.
From this mixture good cupels are
made
, though far better ones are obtained from equal portions of ashes of
burnt
hide scrapings, ashes of the bones of heads of sheep and calves, and
ashes
of deer horns.
But the best of all are produced from deer horns alone,
burnt
to powder; this kind, by reason of its extreme dryness, absorbs metals
least
of all.
Assayers of our own day, however, generally make the
cupels
from beech ashes.
These ashes, after being prepared in the
manner
just described, are first of all sprinkled with beer or water, to make
them
stick together, and are then ground in a small mortar.
They are ground
again
after being mixed with the ashes obtained from the skulls of beasts or from
the
spines of fishes; the more the ashes are ground the better they are.
Some rub bricks and sprinkle the dust so obtained, after sifting it, into the
beech
ashes, for dust of this kind does not allow the hearth-lead to absorb
the
gold or silver by eating away the cupels.
Others, to guard against the
same
thing, moisten the cupels with white of egg after they have been made,
and
when they have been dried in the sun, again crush them; especially if they
want
to assay in it an ore or copper which contains iron.
Some moisten the
ashes
again and again with cow's milk, and dry them, and grind them in a
small
mortar, and then mould the cupels.
In the works in which silver
is
separated from copper, they make cupels from two parts of the ashes of
the
crucible of the cupellation furnace, for these ashes are very dry, and from
one
part of bone-ash.
Cupels which have been made in these ways also
need
to be placed in the sun or in a furnace; afterward, in whatever way
they
have been made, they must be kept a long time in dry places, for the
older
they are, the dryer and better they are.

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