Einstein, Albert.
'Folgerungen aus den Capillaritaetserscheinungen'.
Annalen der Physik,
4
3
(1901)
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<
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">wobei natürlich
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eine andere Constante bedeutet. Nun
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könnten wir aber das zweite Glied der rechten Seite dieser
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Gleichung der Differenz
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gleich setzen -- wobei
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die moleculare Verdampfungswärme (Dampfwärme
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Mole-
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cularmasse),
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das mechanische Aequivalent der Calorie,
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den
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Atmosphärendruck in absolutem Maass und
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das Molecular-
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volum des Dampfes ist --, wenn die potentielle Energie des
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Dampfes Null wäre und wenn für Siedetemperatur der Inhalt
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an kinetischer Energie beim Uebergang vom flüssigen in den
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Gaszustand ungeändert bliebe. Die erste dieser Annahmen
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scheint mir unbedenklich. Da wir aber zu der letzteren An-
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nahme keinen Grund haben, aber auch keine Möglichkeit die
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fragliche Grösse abzuschätzen, so bleibt uns nichts anderes
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übrig, als die obige Grösse selbst zur Rechnung zu </
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<
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im Wärmemaass eingetragen, wobei
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die um die
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äussere Verdampfungsarbeit (in Wärmemaass) verminderte Ver-
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dampfungswärme bedeutet. In die zweite setzte ich die Grössen
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<
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wie sie aus den Capillaritätsversuchen ermittelt sind; in
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der dritten finden sich die Quotienten beider Werte. Isomere
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Verbindungen sind wieder zu einer Zeile </
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id
="
TBL-3-11-2
"
class
="
td00
">C
<
sub
>
<
span
class
="
cmr-8
">10</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">10</
span
>
</
sub
>
O
<
sub
>
<
span
class
="
cmr-8
">2</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-11-3
"
class
="
td00
"> 1464 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-11-4
"
class
="
td00
"> 611 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-11-5
"
class
="
td01
"> 2,51 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-12-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-12-1
"
class
="
td10
">Benzol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-12-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">6</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">6</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-12-3
"
class
="
td00
"> 795 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-12-4
"
class
="
td00
"> 310 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-12-5
"
class
="
td01
"> 2,57 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-13-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-13-1
"
class
="
td10
">Toluol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-13-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">7</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">8</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-13-3
"
class
="
td00
"> 902 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-13-4
"
class
="
td00
"> 372 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-13-5
"
class
="
td01
"> 2,48 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-14-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-14-1
"
class
="
td10
">Aethylbenzol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-14-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">8</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">10</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-14-3
"
class
="
td00
"> 1005 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-14-4
"
class
="
td00
"> 424 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-14-5
"
class
="
td01
"> 2,37 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-15-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-15-1
"
class
="
td10
">m-Xylol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-15-2
"
class
="
td00
"> ,, </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-15-3
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-15-4
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-15-5
"
class
="
td01
"> </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-16-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-16-1
"
class
="
td10
">Propylbenzol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-16-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">9</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">12</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-16-3
"
class
="
td00
"> 1122 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-16-4
"
class
="
td00
"> 475 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-16-5
"
class
="
td01
"> 2,36 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-17-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-17-1
"
class
="
td10
">Mesitylen </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-17-2
"
class
="
td00
"> ,, </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-17-3
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-17-4
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-17-5
"
class
="
td01
"> </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-18-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-18-1
"
class
="
td10
">Cymol </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-18-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">10</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">14</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-18-3
"
class
="
td00
"> 1213 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-18-4
"
class
="
td00
"> 527 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-18-5
"
class
="
td01
"> 2,30 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-19-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-19-1
"
class
="
td10
">Aethylformiat </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-19-2
"
class
="
td00
"> C
<
sub
>
<
span
class
="
cmr-8
">8</
span
>
</
sub
>
H
<
sub
>
<
span
class
="
cmr-8
">6</
span
>
</
sub
>
O
<
sub
>
<
span
class
="
cmr-8
">2</
span
>
</
sub
>
</
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-19-3
"
class
="
td00
"> 719 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-19-4
"
class
="
td00
"> 249 </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-19-5
"
class
="
td01
"> 2,89 </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-20-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-20-1
"
class
="
td10
">Methylacetat </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-20-2
"
class
="
td00
"> ,, </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-20-3
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-20-4
"
class
="
td00
"> </
td
>
<
td
align
="
center
"
style
="
white-space:nowrap; text-align:center;
"
id
="
TBL-3-20-5
"
class
="
td01
"> </
td
>
</
tr
>
<
tr
valign
="
baseline
"
id
="
TBL-3-21-
">
<
td
align
="
left
"
style
="
white-space:nowrap; text-align:left;
"
id
="
TBL-3-21-1
"
class
="
td10
"> </
td
>
</
tr
>
</
table
>
</
div
>
</
body
>
</
html
>
